主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2021, Vol. 40 ›› Issue (5): 730-734.

• • 上一篇    下一篇

碳材料对水性膨胀涂料阻燃抑烟性能的影响

付士健1,龙海洋2   

  1. 1. 黄大铁路有限责任公司,山东东营257000;2. 中南大学土木工程学院,湖南长沙410075
  • 出版日期:2021-05-15 发布日期:2021-05-15
  • 作者简介:付士健(1980-),男,安徽宿州人,黄大铁路有限责任公司高级工程师,硕士,主要从事钢结构抗火研究,山东省东营市东营区南一路226 号,257000。
  • 基金资助:
    国家自然科学基金项目(51578163)

Effect of carbon materials on the flame retardant and smoke suppression performance of waterborne intumescent coatings

FU Shi-jian1,LONG Hai-yang2   

  1. 1. Huangda Railway Co., Ltd., Shandong Dongying 257000, China; 2. School of Civil Engineering, Central South University, Hunan Changsha 410075, China
  • Online:2021-05-15 Published:2021-05-15

摘要: 以膨胀石墨(EG)、碳纳米管(CNTs)、富勒烯(C60)、石墨烯(Gr)为填料,研究其在水性膨胀涂料中的阻燃性、热稳定性、抑烟性和耐水性碳材料对水性膨胀涂料防火抑烟性能的影响。用扫描电镜(SEM)、傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)和粒度分布对碳层进行了表征。结果表明:碳材料可以有效提高水性膨胀涂料的防火性能,受热300 s 时,涂覆防火涂料的板背面温度比无防火涂料的钢板降低了50%,且加入碳材料的防火涂料更能隔热;SP-Gr 的炭层膨胀系数最大,约为未加入碳材料涂料的两倍,且高温加热下加入Gr 的涂料具有最大的炭残余质量;加入碳材料的防火涂料阻烟效果更好,烟密度降低30%以上;加入Gr 的涂料具有最好的耐水性。在水性防火涂料中掺入石墨烯具有最好的性能。

关键词: 水性防火涂料, 抑制烟雾, 涂层, 碳材料

Abstract: This study uses expanded graphite (EG), carbon nanotubes (CNTs), fullerene (C60), and graphene (Gr) as fillers to study their performance as the flame retardancy, thermal stability, smoke suppression and water resistance in water-based intumescent coatings. The effect of carbon materials on the fire and smoke suppression performance in water-based intumescent coatings was studied. The carbon layer was characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), X- ray diffraction (XRD) and particle size distribution. The test results show that carbon materials can effectively improve the fireproof performance of water-based intumescent coatings. When heated for 300 s, the temperature of the back of the board coated with the fireproof coating is 50% lower than that of the steel plate without fireproof coating, and the fireproof coating with carbon materials have better heat insulation; SP-Gr has the largest expansion coefficient of the carbon layer, which is about twice that of no carbon material coating, and the coating with Gr added under high temperature heating has the largest carbon residual weight; the fire retardant coating with carbon material has a better smoke resistance effect. The density is reduced by more than 30%; the coating with Gr has the best water resistance. In this study, adding graphene to water-based fireproof coatings has the best performance.

Key words: waterborne intumescent coating, smoke suppression, coating, carbon material