主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2020, Vol. 39 ›› Issue (2): 157-161.

• • 上一篇    下一篇

溶剂型氯丁胶对汽油鉴定的干扰

薛腾,张金专   

  1. (中国人民警察大学,河北廊坊065000)
  • 收稿日期:2019-09-22 出版日期:2020-02-15 发布日期:2020-02-15
  • 通讯作者: 张金专(1973-),男,中国人民警察大学消防工程系副主任,教授。
  • 作者简介:薛 腾(1995-),男,山东潍坊人,中国人民警察大学研究生一队硕士研究生,主要从事火灾调查和火灾物证鉴定方面的研究,河北省廊坊市西昌路220号,065000。
  • 基金资助:
    公安技术交流培训计划项目“基于移动终端的火灾调查辅助系统”

Interference of solvent-type neoprene on gasoline identification

XUE Teng, ZHANG Jin-zhuan   

  1. (China People's Police University, Hebei Langfang 065000, China)
  • Received:2019-09-22 Online:2020-02-15 Published:2020-02-15

摘要: 基于气相色谱-质谱法和裂解气相色谱-质谱法,将得到的氯丁胶溶剂、胶体及其燃烧残留物谱图与120#汽油原样及其燃烧残留物谱图进行对比。结果表明:氯丁胶溶剂原样谱图与120#汽油谱图相似度较高,但仍存在不同,氯丁胶溶剂中甲苯含量较高,120#汽油中不含甲苯。120#汽油燃烧残留物和溶剂型氯丁胶燃烧残留物中均可以检测出芳香烃,稠环芳烃类传统燃料汽油中的特征组分,会对传统燃料汽油的鉴定产生干扰。如果在检测样品中发现26-二叔丁基对甲苯酚、1-叔丁基-2-甲氧基-4-甲基苯,则可以排除溶剂型氯丁胶对汽油的干扰。实验结果可为氯丁胶等粘合剂火灾物证鉴定工作提供参考。

关键词: 氯丁胶, GC-MS分析, 燃烧残留物, 火灾调查

Abstract: Based on gas chromatography-mass spectrometry and pyrolysis gas chromatography-mass spectrometry, the obtained neoprene solvent, colloid and its combustion residue spectrum were compared with the 120# gasoline sample and its combustion residue spectrum. The results showed that the original spectrum of the chloroprene solvent and the 120# gasoline spectrum were similar, but there were still differences. The toluene content in the chloroprene solvent was higher, and the toluene was not contained in the 120# gasoline. The aromatic components of 120# gasoline burning residue and neoprene combustion residue can be detected, and the characteristic components in the traditional fuel gasoline of fused aromatic hydrocarbons will interfere with the identification of traditional fuel gasoline. If 2,6-di-tert-butyl-p-cresol is found in the test sample, 1-tert-butyl-2-methoxy-4-methylbenzene can eliminate the interference of neoprene on gasoline. The experimental results can provide reference for the identification of adhesive fire evidence such as neoprene.

Key words: neoprene, GC-MS analysis, combustion residue, fire investigation