主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2023, Vol. 42 ›› Issue (10): 1322-1327.

• • 上一篇    下一篇

纳米纤维材料对锂电池热失控传播影响研究

张青松1,2, 杨铠宾1,2, 赵洋1,2   

  1. (1. 中国民航大学 安全科学与工程学院,天津 300300; 2. 民航热灾害防控与应急重点实验室,天津 300300)
  • 出版日期:2023-10-15 发布日期:2023-10-15
  • 作者简介:张青松(1977- ),男,中国民航大学安全科学与工程学院教授,博士,主要从事锂电池热失控的研究,天津市东丽区新立街道,300300。
  • 基金资助:
    基金项目:国家自然科学基金民航联合基金重点支持项目(U2033204)

Effect of nanofiber material on thermal runaway propagation of lithium battery

Zhang Qingsong1,2, Yang Kaibin1,2, Zhao Yang1,2   

  1. (1. School of Safety Science and Engineering, Civil Aviation University of China, Tianjin 300300, China; 2. Key Laboratory of Civil Aviation Thermal Disaster Prevention and Emergency Response, Tianjin 300300, China)
  • Online:2023-10-15 Published:2023-10-15

摘要: 锂电池在运输以及使用过程中的磕碰、外短路等原因造成的热失控极易诱发周边电池升温,导致热失控蔓延。为控制锂电池热失控传播,本文使用纳米纤维材料对热量传播进行抑制,以瓦楞纸、陶瓷纤维和玻璃纤维作为间隔材料展开锂电池热失控试验,从隔热性和耐火性两方面对隔热材料进行评估。结果表明:虽然纳米纤维材料的保温性能会促使首节电池更快进入热失控状态,但由于其良好的隔热性能,锂电池热失控的传播可以被有效抑制。对首节电池燃爆过程中隔热材料的热流密度进行测算,发现陶瓷纤维纸的热通量峰值更低,纳米纤维材料的隔热性能要优于瓦楞纸。同时对3种材料耐火性进行试验,判定电池燃爆时材料的可靠性,发现瓦楞纸极易燃烧,而纳米纤维材料具有良好的热稳定性。结果证明了纳米材料作为锂电池运输间隔材料的可行性。

关键词: 锂电池, 热失控传播, 纳米纤维材料, 燃爆, 温度

Abstract: The thermal runaway of lithium battery caused by bumping and external short circuit during transportation and use is very easy to induce the surrounding batteries to heat up, leading to the spread of thermal runaway. In order to control the thermal runaway propagation of lithium batteries, this paper uses nanofiber materials to inhibit heat propagation, and uses corrugated paper, ceramic fiber and glass fiber as spacer materials to carry out the thermal runaway test of lithium batteries, and evaluates the insulation materials in terms of heat insulation and fire resistance. The results show that although the thermal insulation performance of the nanofiber material will prompt the first battery to enter the thermal runaway state faster, the propagation of the thermal runaway of the lithium battery can be effectively suppressed due to its good thermal insulation performance. The heat flux density of the thermal insulation materials during the combustion explosion of the first battery is measured, and it is found that the peak heat flux of ceramic fiber paper is lower, and the thermal insulation performance of nanofiber materials is better than that of corrugated paper. At the same time, the fire resistance of the three materials was tested to determine the reliability of the materials during the battery explosion, and it was found that the corrugated paper was very easy to burn, while the nanofiber material had good thermal stability. The results demonstrate the feasibility of nanomaterials as transportation spacers for lithium batteries.

Key words: lithium battery, thermal runaway propagation, nanofiber material, ignition and explosion, temperature